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'Cesium Compound' in keywords Facet   section ZfN Section B  [X]
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1998 (1)
1981 (1)
1Author    Herbert Jacobs, Bernd HarbrechtRequires cookie*
 Title    Eine neue Darstellungsmethode für Caesiumhydroxid A New Preparative Method for Cesiumhydroxide  
 Abstract    Cesiumhydroxide has been prepared by the reaction of CsOH • H2O with CSNH2 in super-critical ammonia. Thermochemical data for CsOH are given in the range from 100 to 640 K. The x-ray investigation of the compound above 497.5 K shows a sodium chloride type of struc-ture with a = 6,427 (5) A at 503 K. The lattice constants for the rhombic modification at 298 K are a = 4,350 (3) A, b = 11,99 (1) A and c = 4,516 (3) A. The cell contains four formula units. The structure is of an anii-NaOH type. 
  Reference    Z. Naturforsch. 36b, 270—271 (1981); eingegangen am 14. November 1980 
  Published    1981 
  Keywords    Cesium Compound, Hydroxide, Thermal and Crystal Data 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0270_n.pdf 
 Identifier    ZNB-1981-36b-0270_n 
 Volume    36 
2Author    Z. NaturforschRequires cookie*
 Title    Untersuchungen an Polyhalogeniden, X X X IY  
 Abstract    [1] Cäsium(18-Krone-6)dichloroiodat(I), [Cs(C12H 240 6)]IC12 S tu d ies o n P olyhalides, X X X IV [1] C e siu m (1 8 -cro w n -6)d ich lo ro io d ate , [C s(C 12H 240 6)]IC12 M e rv a t E l E ssa w i3, K arl-F rie d ric h T e b b e * b a Chemical D epartm ent, The new compound [Cs(18-crown-6)]ICl2 has been prepared by the reaction of cesium chloride and 18-crown-6 with iodine chloride in ethanol and structurally characterized by X-ray diffrac­ tion methods. The geometries of the cation [Cs(18-crown-6)]+ and of the anion IC12~ are as expected. 
  Reference    Z. Naturforsch. 53b, 263—265 (1998); eingegangen am 5. November 1997 
  Published    1998 
  Keywords    Polyhalogenide, Dichloroiodate, Crown Complex, Cesium Compound, Crystal Structure 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0263_n.pdf 
 Identifier    ZNB-1998-53b-0263_n 
 Volume    53