| | 1 | Author
| A. Gordon, FrancisJ. Disalvo | Requires cookie* | | | Title
| R obert  | | | | Abstract
| The ternary compound Ce8Pd24Sb is very close in composition to the intermediate valent binary CePd3. A single crystal study yielded a cubic cell with a = 8.461 (1)A, Pm3m symmetry with wR2 = 0.0412 based on 1453 reflections (222 unique) and 16 parameters. This new structure type is composed of distorted perovskite and Cu3Au subcells arranged with the perovskite-like units centred on the corners of the cube. Fitting the magnetic susceptibility data above 100K to a Curie-Weiss expression yielded a Weiss constant of -15(3)K (anti ferromagnetic) and an effective high temperature moment per cerium of 2.45(4)/<B indicating trivalent cerium. No ordering was observed above 3K. | | | |
Reference
| (Z. Naturforsch. 51b, 52—5 [1996]; received May 17 1995) | | | |
Published
| 1996 | | | |
Keywords
| Cerium Intermetallic, Crystal Structure, Magnetic Susceptibility | | | |
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| default:Reihe_B/51/ZNB-1996-51b-0052.pdf | | | | Identifier
| ZNB-1996-51b-0052 | | | | Volume
| 51 | |
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