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'Cationic Carbyne Complexes' in keywords Facet   Publication Year 1982  [X]
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1Author    ErnstOtto Fischer, Jiabi Chen, Ulrich SchubertRequires cookie*
 Title    Übergangsmetall-Carben-Komplexe, CXXVI [1] Darstellung und Struktur symmetrischer Hydroxycarben-Anhydrid-Komplexe des Mangans und Rheniums Transition Metal Carbene Complexes, CXXVI [1] Preparation and Structure of Symmetrica! Hydroxycarbene Anhydride Complexes of Manganese and Rhenium  
 Abstract    Symmetrical anhydrides of hydroxycarbene complexes of manganese and rhenium, [JT-C5H5(C0)2MC(R)]20, (M = Mn, Re) are prepared by reaction of cationic carbyne com-plexes [.T-C5HÖ(CO)2MCR]BX4 with the corresponding metal carbonyl acylates Li[7r-C5H5(C0)2MC(0)R]. [^-C5H5(CO)2MnC(C6H5)]20 is also obtained by controlled hydrolysis of Tr-CsH^CO^MnCXBrJCeHs. The new complexes are characterized spectro-scopically and by an X-ray structure analysis of [jr-CsH^CO^MnQCeHs^O. Bei der Reaktion von Pentacarbonyldiethyl-aminocarbin-chrom-tetrafluorborat, [(CO)5CrCNEt2]BF4, mit NMe4[(C0)5MC(0)R] (M = Cr, W) entstehen die gemischten Hydroxy-carben-Anhydrid-Komplexe 
  Reference    Z. Naturforsch. 37b, 1284—1288 (1982); eingegangen am 7. Juni 1982 
  Published    1982 
  Keywords    Cationic Carbyne Complexes, Metal Acylates, Bromocarbene Complex, Molecular Structure 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1284.pdf 
 Identifier    ZNB-1982-37b-1284 
 Volume    37