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'Cationic ^ T hiocarbene Complexes' in keywords Facet   section ZfN Section B  [X]
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1990 (1)
1Author    N. Ullrich, C. Stegmair, H. Keller, E. Herdtweck, F. R. KreißlRequires cookie*
 Title    Darstellung und Struktur kationischer i^-Thiocarbenkomplexe von Molybdän und Wolfram Synthesis and Structure of Cationic //2-Thiocarbene Complexes of Molybdenum and Tungsten  
 Abstract    The reaction o f dim ethyl(m ethylthio)sulfonium tetrafluoroborate [(CH-,)-,S-SCH3][BF4] with //;'-cyclopentadienyl(dicarbonyl)carbyne com plexes o f molybdenum and tungsten Cp(CO)2M = C -R (M = M o. W; R = C H ,, C6H 5, C6H4C H 3) lc , 2 a ~ d results in an electrophilic attack o f the SCH, moiety at the metal carbon triple bond, providing orange to red, diam ag­ netic, cationic //--thiocarbene com plexes [Cp(CO):M = C(R)$CH,J[BF4] 3c, 4 a ~ d in high yields. The new com pounds were identified by X-ray structure analysis, N M R , IR and mass spectra. 
  Reference    Z. Naturforsch. 45b, 921 (1990); eingegangen am 9. November 1989 
  Published    1990 
  Keywords    Cationic ^-T hiocarbene Complexes, M olybdenum Tungsten, X-Ray 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-0921.pdf 
 Identifier    ZNB-1990-45b-0921 
 Volume    45