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'Carbyne Complex' in keywords Facet   Publication Year 1980  [X]
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1980[X]
1Author    Olli Orama, Ulrich Schubert, FritzRoland Kreißl, ErnstOtto FischerRequires cookie*
 Title    Übergangsmetall-Carbin-Komplexe, LVI [1] Umsetzung eines kationischen Carbin-Komplexes mit einem Carbonylmetallat. Der Phenylketenyl-Rest als Briickenhgand Transition Metal Carbyne Complexes, LVI [1] Reaction of a Cationic Carbyne Complex with a Carbonylmetalate. The Phenylketenyl Group as a Bridging Ligand  
 Abstract    By reaction of [(jr^HsHCOfeMnEEC-CeHslBCLi with NaRe(CO)5 a new type of complex is obtained. It crystallizes in the monoclinic space group P 2i/c, Z = 4, a — 1115(1), b= 1464(1), c= 1657(2) pm, ß= 136.79(8)°. Structure determination reveals a binuclear complex, the Mn-Re bond (281.7(3) pm) of which is bridged by the a-carbon atom of a phenylketenyl group (Mn-C 221(3), Re-C 224(3) pm) and semi-bridged by a CO group (Mn-C 187(4), Re-C 254(4), Mn-C-0 160(3)°). 
  Reference    (Z. Naturforsch. 35b, 82—85 [1980]; eingegangen am 2. Oktober 1979) 
  Published    1980 
  Keywords    Carbyne Complex, X-ray, Metal-Metal Bond 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0082.pdf 
 Identifier    ZNB-1980-35b-0082 
 Volume    35