| | 1 | Author
| Prof Sonderdruckanforderungen, M. Dr, Herberhold | Requires cookie* | | | Title
| Monosubstituierte Derivate des Halbsandwich-Komplexes Cp*Ta(CO)4 - Vergleich mit den analogen Vanadiumverbindungen Cp*V(CO)3L und Röntgenstrukturanalyse des y-Picolin-Komplexes Cp*V(CO)3(NC5H4-Me(4))  | | | | Abstract
| M onosubstituted D erivatives o f the H alfsandw ich C om plex C p*T a(C O)4 -C om parison with the A nalogous V anadium C om pounds C p*V (C O)3L and X -R ay Structural Analysis of the y-Picoline C om plex C p*V (C O)3(N C 5H 4-M e(4)) M ax H erberhold*, G udrun F rohm ader, Jürgen P eu k ert und W olfgang Milius The photo-induced substitution of a CO ligand in Cp*Ta(CO)4 (1) has been used to pre pare a series of Cp*Ta(CO)3L (2) complexes, in which the two-electron ligand L includes, e.g., isonitriles, sulfanes, cyclic ethers, phosphanes and pyridines. The complexes (2 a -y) were characterized by their v(CO) frequencies and their 'H and 13C NM R spectra, and were compared -if possible -with the corresponding vanadium complex, C p*V(C O)4 (3) and its derivatives, C p*V(C O)3L (4). The molecular structure o f the 4-picoline complex Cp*V(C O)3(NC5H 4-M e(4)) (4r) has been determ ined by X-ray crystal structure analysis. | | | |
Reference
| Z. Naturforsch. 55b, 1188—1194 (2000); eingegangen am 21. August 2000 | | | |
Published
| 2000 | | | |
Keywords
| Halfsandwich Complexes, Carbonylmetal Compounds, Photoreactions | | | |
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| default:Reihe_B/55/ZNB-2000-55b-1188.pdf | | | | Identifier
| ZNB-2000-55b-1188 | | | | Volume
| 55 | |
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