| | 1 | Author
| Friedrich-Wilhelm Grevels, Konrad Schneider, Carl Krüger, Richard Goddard | Requires cookie* | | | Title
| Tricarbonyl(^ 4 -1.5-cümethylen-2.6-cümethylcyclooctan)eisen: photochemische Synthese und Struktur Tricarbonyl(^ 4 -l,5-dimethylene-2,6-dimethylcyclooctane)iron: Photochemical Synthesis and Structure  | | | | Abstract
| Extended photolysis of pentacarbonyliron in neat 2,3-dimethylbutadiene results in dimerization of the diene and formation of tricarbonyl(?y 4 -l,5-dimethylene-2,6-dimethyl-cyclooctane)iron (1). The structure of complex 1 is characterized by a trigonal-bipyramidal geometry whereby the exocyclic double bonds of the diene ligand and one of the carbonyl groups lie exactly in the equatorial coordination plane. | | | |
Reference
| Z. Naturforsch. 35b, 360—365 (1980); eingegangen am 5. November 1979 | | | |
Published
| 1980 | | | |
Keywords
| Carbonyliron Olefin Complexes, Dimerization of Dimethylbutadiene, Photochemistry, NMR, X-ray | | | |
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| default:Reihe_B/35/ZNB-1980-35b-0360.pdf | | | | Identifier
| ZNB-1980-35b-0360 | | | | Volume
| 35 | |
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