| | 1 | Author
| A. Döhring, P. W. Jolly, C. Krüger, M. J. Romão | Requires cookie* | | | Title
| The Ni(0)—C0 2 System: Structure and Reactions of [Ni(PCy 3 ) 2 (i/ 2 -C0 2 )]  | | | | Abstract
| The reactions of a variety of bis(tricyclohexylphosphine)nickel species with C0 2 have been studied. The product of the reaction is solvent dependent: in toluene the known complex [NiL 2 (/7 : -C0 2)]-toluene (L = PCy 3) is formed while in ether or pentane a binuclear complex [(NiL 2) 2 (?;-C0 2)] results through the intermediacy of the solvent free species [NiL 2 (// 2 -C0 2)] the structure of which has been determined by X-ray crystallography. | | | |
Reference
| Z. Naturforsch. 40b, 484—488 (1985); received November 30 1984 | | | |
Published
| 1985 | | | |
Keywords
| Carbon Dioxide Complexes, Nickel, X-Ray | | | |
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| default:Reihe_B/40/ZNB-1985-40b-0484.pdf | | | | Identifier
| ZNB-1985-40b-0484 | | | | Volume
| 40 | |
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