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| Borylated Carbodiimides, Wolfgang Einholz, Wolfgang Haubold | Requires cookie* | | | Title
| Borylierte Carbodiimide  | | | | Abstract
| The borylated carbodiim ides 3 a, 3b and 4 can be synthesized by reaction o f the 2-ch loro-l,3,2-diazaborolidines 2 a, 2b with M e3Si —N = C —N —SiM e3 (1) or M e3Si —N = C = N —'Bu respectively. In the reaction of the non cyclic haloboranes R 2BH al (R = Ph, M e, M e2N) 2 c —e with 1 R3B is formed and for R = M e, M e2N polym eric (R BN C N)" is obtained, whilst the spectroscopically identified intermediate products only in the case o f R = Ph can be isolated. The chloroborolane 2 f leads to the polymeric diborylated carbodiim ide 3f, probably due to intermolecular B —N-coordi-nation. H2N —CN forms with 9-BBN the m onoborylated cyanam ide 8 . | | | |
Reference
| Z. Naturforsch. 41b, 1367—1372 (1986); eingegangen am 3. A p ril/14. August 1986 | | | |
Published
| 1986 | | | |
Keywords
| Boron-Nitrogen C om pounds, Carbodiim ides, Synthesis, Structure, Spectral Data | | | |
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| default:Reihe_B/41/ZNB-1986-41b-1367.pdf | | | | Identifier
| ZNB-1986-41b-1367 | | | | Volume
| 41 | |
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