| | 1 | Author
| WolfPeter Fehlhammer, Eberhard Bär, Borislav Boyadjiev | Requires cookie* | | | Title
| Chemie der Isoblausäure  | | | | Abstract
| , II [1] Reaktionen von [M(CO)5CNH] (M = Cr, Mo, W) mit Aziridinen: Zyklische Diaminocarbenkomplexe Chemistry of Hydrogen Isocyanide, II [1] Reactions of [M(CO)5CNH] (M = Cr, Mo, W) with Aziridines: Cyclic Diaminocarbene Complexes The hydrogen isocyanide com plexes [M (C O)5CNH] (M = Cr, M o, W) have been treated with the aziridines R N C H R 'C H 2 (R = H, R' = H, Me, Et; R = M e, R' — H) to give im idazolidin-2-ylidene com plexes. The sam e type of ligand forms on addition of aziridine to the electrophilic isocyanide group in [FpC N Ph]+ in the presence of B r'. IR, 'H N M R , 13C N M R and mass spectra of the new com pounds are reported. | | | |
Reference
| Z. Naturforsch. 41b, 1023—1027 (1986); eingegangen am 14. April 1986 | | | |
Published
| 1986 | | | |
Keywords
| Functionalized Isocyanides, Reactions at Coordinated Ligands, Ring O pening and Closure, Carbene C om plexes | | | |
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| default:Reihe_B/41/ZNB-1986-41b-1023.pdf | | | | Identifier
| ZNB-1986-41b-1023 | | | | Volume
| 41 | |
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