1 | Author | N. Orbert Kuhn3, Hans Bohnen3, GeraldH. Enkelb | Requires cookie* |
Title | Zur Reaktion von Carben-Addukten des Kohlenstoffdisulfids mit Brom und Iod [1] On the Reaction of Carbene Adducts of Carbon Disulfide with Bromine and Iodine [1] ![]() | ||
Abstract | The carbene adducts 3 are obtained as stable solids from the im idazol-2-ylidenes 1 and CS2. 3 c reacts with bromine to give the cationic bromosulfane 4, whereas iodine forms the charge-transfer adduct 5. Oxidative coupling to the dicationic disulfane 6 is observed with excess of iodine. The X-ray structure analyses of 3b, 4, 5 and 6 are reported. | ||
Reference | Z. Naturforsch. 49b, 1473—1480 (1994); eingegangen am 7. Juli 1994 | ||
Published | 1994 | ||
Keywords | Carbene Adducts, X-Ray, Iodine Reaction, Bromine Reaction | ||
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