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1978 (1)
1Author    Hans-Georg Von Schnering, Wolfgang MayRequires cookie*
 Title    Die Struktur des 2  
 Abstract    One of the diastereomeres of 2,3,4,6,7,8-hexamethyl-2,3,4,6,7,8-hexaphosphabicyclo-[3,3,0]octane (PMe)öC2H2 crystallizes in the space group P2i/n with four molecules per unit cell. Two independent molecules are nearly identical in shape but differ by inter-molecular packing. The five-membered rings have a skew chair conformation with all exocyclic methyl groups in axial positions leading to a staggered all-trans conformation of the bicyclic system. The mean bond lengths are P-P = 220.9 pm, P-C = 185.9 pm and C-C = 151.9 pm. 
  Reference    Z. Naturforsch. 33b, 698—698 (1978); eingegangen am 24. April 1978 
  Published    1978 
  Keywords    Carbaphosphane, Molecular Structure, Crystal Structure 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0698.pdf 
 Identifier    ZNB-1978-33b-0698 
 Volume    33