| | 1 | Author
| H. Erbert, W. Roesky, Mathias Noltem, GeorgeM. Sheldrick | Requires cookie* | | | Title
| Synthese und Struktur des Trifluoracetyldicyanomethanids Synthesis and Structure of Trifluoroacetyldicyanom ethanide  | | | | Abstract
| A suspension of NaCN in CH3CN was treated with excess of C2F4. The resulting red solution was evaporated to dryness and a red amorphous solid remained. One part of this solid was dissolved in water and a solution of Ph4AsCl was added. During the work-up procedure two salts were isolated, yellow [Ph4A s'][C F 3C (0)C (C N)2~] l a and red [Ph4A s+][(NC)2CC(CN)C(F)NC(CN)2_] 2a. The products were characterized on the basis of field desorption mass spectroscopy for positive and negative ions, l a was further characterized by an X-ray single crystal investigation. | | | |
Reference
| Z. Naturforsch. 40b, 883 (1985); eingegangen am 7. März 1985 | | | |
Published
| 1985 | | | |
Keywords
| X-Ray, Carbanion, Fluorine, Nitrile | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/40/ZNB-1985-40b-0883.pdf | | | | Identifier
| ZNB-1985-40b-0883 | | | | Volume
| 40 | |
|
