| | 1 | Author
| Rolf Minkwitz, Thomas Hertel, Uwe Zachwieja | Requires cookie* | | | Title
| Reaktion von Cacodylsäure (CF^^AsOOH im System HF / MF5 (M = As, Sb) und Kristallstruktur von Difluordimethylarsonium- hexafluoroantimonat (CH3)2AsF2SbF6 Reaction of Cacodylic Acid (CH3)2AsOOH in the System HF / MF5 (M = As, Sb), and Crystal Structure of Difluorodimethylarsonium Hexafluoroantimonate  | | | | Abstract
| In the reaction of cacodylic acid (CH3)2AsOOH in the superacid system HF / MF5 (M = As, Sb) the difluorodimethylarsonium hexafluorometallates [(CH3)2AsF2]MF6 are formed and have been characterized by i.r. and Raman spectroscopy. The crystal structure of the hexafluoroanti monate has been determined at -100°C (orthorhombic space group Ibca with Z = 4, a = 10.973, b = 11.164, c = 14.200 pm). | | | |
Reference
| Z. Naturforsch. 52b, 1185—1190 (1997); eingegangen am 1. Juli 1997 | | | |
Published
| 1997 | | | |
Keywords
| Difluorodimethylarsonium Hexafluorometallates, Cacodylic Acid, Crystal Structure, Super Acid | | | |
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| default:Reihe_B/52/ZNB-1997-52b-1185.pdf | | | | Identifier
| ZNB-1997-52b-1185 | | | | Volume
| 52 | |
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