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1999 (1)
1Author    Andreas Böhm, Kurt Polborn, Wolfgang BeckRequires cookie*
 Title    Metal Complexes of Biologically Important Ligands, CX [1]. Orthopalladation of N-(Diphenylmethylene) Schiff Bases from Peptide Esters -C,N versus C,N,0 Coordination -Crystal Structure of ClPd[C6H4(C6H5)C=N(Gly-L-Pr0-L-Ala-OMe)-C,N,O] with cis/trans Peptide Bonds  
 Abstract    The reaction of the N-(diphenylmethylene) Schiff base from glycyl-L-prolyl-L-alanine methyl ester 1 with tetrachloropalladate in the presence of sodium acetate affords the or-thopalladated bicyclic C ,N ,0 chelate 2. Complex 2 was characterized by X-ray diffraction. Remarkably, the unit cell contains two independent molecules, the cis isomer 2a and the trans 
  Reference    Z. Naturforsch. 54b, 300—304 (1999); received October 10 1998 
  Published    1999 
  Keywords    N-(Diphenylmethylene) Peptide Esters, Orthopalladation, C, N, 0 Chelate, cis/trans Peptide Bonds 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0300.pdf 
 Identifier    ZNB-1999-54b-0300 
 Volume    54