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'Bromo Complexes' in keywords Facet   Publication Year 1993  [X]
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1993[X]
1Author    Karin Oldenburg, Arnd VoglerRequires cookie*
 Title    Electronic Spectra and Photochemistry of Tin(II), Lead(II), Antimony(III), and Bismuth(III) Bromide Complexes in Solution  
 Abstract    The electronic spectra o f brom o complexes o f main group metal ions with an s2 electronic configuration (SnBr3~, PbBr3~, PbBr42_, SbBr4~, SbBr63~, BiBr4~, BiBr63~) in acetonitrile show long-wavelength absorption bands which are assigned to metal-centered sp transitions. C om ­ pared to the corresponding chloro complexes the sp bands o f the bromo complexes appear at longer wavelength due to sp/LM C T mixing (LM CT = ligand-to-metal charge transfer). As a result o f this mixing the luminescence which originates from low-energy sp excited states is much weaker than that o f the chloro complexes. M oreover, some o f the bromo complexes (e.g. BiBr4~) undergo a photochemical redox decom position induced by LMCT excitation. 
  Reference    Z. Naturforsch. 48b, 1519—1523 (1993); received July 1 1993 
  Published    1993 
  Keywords    Electronic Spectra, Bromo Complexes, Main Group M etals, Photochemistry 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1519.pdf 
 Identifier    ZNB-1993-48b-1519 
 Volume    48