| | 1 | Author
| S. Münchau, Hk Müller-Buschbaum | Requires cookie* | | | Title
| Cd0,73 Cu0,27V2 O 6: A Com pound with Brannerite Structure  | | | | Abstract
| Single crystals of Cd() 73Cu<,.27V 20 6 were prepared by solid state reactions. X-ray investiga tions lead to monoclinic symmetry, space group C \h-C2lm , a = 9.339, b = 3.5604, c = 6.893 A , ß = 111.85°, Z = 2. It belongs to the Brannerite structure, showing a statistical distribution of Cd2+ and Cu2+ on one point position. The crystal structure of Brannerites is discussed with respect to the distorted O 2-octahedra around V 5+ and the influence of the Jahn-Teller active Cu-+ ion to the shortened M2+Oa octahedra. | | | |
Reference
| Z. Naturforsch. 49b, 927 (1994); eingegangen am 4. März 1994 | | | |
Published
| 1994 | | | |
Keywords
| Cadmium, Copper, Vanadium, Oxide, Brannerite Type | | | |
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| default:Reihe_B/49/ZNB-1994-49b-0927.pdf | | | | Identifier
| ZNB-1994-49b-0927 | | | | Volume
| 49 | |
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