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'Brannerite Type' in keywords Facet   Publication Year 1994  [X]
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1Author    S. Münchau, Hk Müller-BuschbaumRequires cookie*
 Title    Cd0,73 Cu0,27V2 O 6: A Com pound with Brannerite Structure  
 Abstract    Single crystals of Cd() 73Cu<,.27V 20 6 were prepared by solid state reactions. X-ray investiga­ tions lead to monoclinic symmetry, space group C \h-C2lm , a = 9.339, b = 3.5604, c = 6.893 A , ß = 111.85°, Z = 2. It belongs to the Brannerite structure, showing a statistical distribution of Cd2+ and Cu2+ on one point position. The crystal structure of Brannerites is discussed with respect to the distorted O 2-octahedra around V 5+ and the influence of the Jahn-Teller active Cu-+ ion to the shortened M2+Oa octahedra. 
  Reference    Z. Naturforsch. 49b, 927 (1994); eingegangen am 4. März 1994 
  Published    1994 
  Keywords    Cadmium, Copper, Vanadium, Oxide, Brannerite Type 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0927.pdf 
 Identifier    ZNB-1994-49b-0927 
 Volume    49