| | 1 | Author
| Gisela Sawitzki, Wolfgang Einholz, Wolfgang Haubold | Requires cookie* | | | Title
| Kristall-und Molekülstruktur von N,N'-Bis(l,3-dimethylbenzo[b]-l,3?2-diazaboroIidin-2-yl)carbodiimid Crystal and Molecular Structure of N,N'-Bis(l,3-dimethylbenzo[b]-l,3,2-diazaborolidin-2-yl)carbodiimide  | | | | Abstract
| Crystals of the title compound (2) are monoclinic with a = 905.5(3), b = 593.6(2). c — 3243.5(8) pm, ß = 95.63(2)°, Z = 4, space group P2 x ln. The molecule 2 neither has a C 2 -symmet-rical allene-type nor a D 2d -symmetrical cumulene-type structure, but it has a non-linear B-N = C=N —B arrangement and is nearly planar. The central N = C=N angle has a value of 171.9(3)°, the B —N = C angles are 145.9(2)° and 163.1(3)°. | | | |
Reference
| Z. Naturforsch. 43b, 1179—1183 (1988); eingegangen am 25. Mai 1988 | | | |
Published
| 1988 | | | |
Keywords
| Boron-Nitrogen Compounds, Borylated Carbodiimides, X-Ray | | | |
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| default:Reihe_B/43/ZNB-1988-43b-1179.pdf | | | | Identifier
| ZNB-1988-43b-1179 | | | | Volume
| 43 | |
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