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'Borates' in keywords Facet   Publication Year 1998  [X]
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1Author    PhilipJ. Bray, GaryL. PetersenRequires cookie*
 Title    NMR and NQR Studies of Borate Glasses  
 Abstract    Nuclear magnetic resonance (NMR) has been used for some 40 years to study atomic arrange-ments, chemical bonding, and structural groupings in borate glasses and crystalline compounds, and nuclear quadrupole resonance (NQR) has more recently increased the resolution and accuracy of the measurements. Examples are presented of the use of first-order and second-order quadrupo-lar effects in "B NMR spectra to obtain structural information, and n B and 10 B NQR spectra to obtain the quadrupolar parameters Q cc (the coupling constant) and 77 (the asymmetry parameter) with accuracies of 5 or 6 significant figures, and 3 figures, respectively. Q cc and 77 are extremely sensitive to changes in atomic rearrangements and chemical bonds, so they are excellent monitors and provide identification of bonding configurations and structural groupings in borates: Examples are also presented in which combinations of NMR and NQR data are used to extract the desired information. NQR detection of resonances at frequencies as low as 276 kHz is discussed. 
  Reference    Z. Naturforsch. 53a, 273—284 (1998); received December 30 1997 
  Published    1998 
  Keywords    NMR, NQR, Borates, Quadrupolar Interactions 
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 TEI-XML for    default:Reihe_A/53/ZNA-1998-53a-0273.pdf 
 Identifier    ZNA-1998-53a-0273 
 Volume    53