| | 1 | Author
| Rolf Minkwitz, Klaus Jänichen, Herbert Prenzel, Volker Wölfel | Requires cookie* | | | Title
| Beiträge zur Chemie der Schwefelhalogenide, 6 [1] Untersuchungen an Trichlorsulfonium(IV)-Salzen Contributions to the Chemistry of Sulfur Halides, 6 [1] Investigations on Trichlorosulfonium(IV) Salts  | | | | Abstract
| The crystal structure of SCl 3 + AsF 6 ~ is reported. The mean S-Cl stretching frequency v of the SC1 3 + cations, weighted according to the degree of degeneration, in the different SC1 3 + X~ salts is directly proportional to the mean S-Cl distance r scl , the force constant f sci and the sulfur.. .anion distance (C1 3 S + .. .X"). That SC1 3 + C1" should be isostructural with PC1 4 ~, the large variation in the S-Cl stretching frequencies in the SC1 3 + X~ salts is due to cation-anion interaction forces. | | | |
Reference
| (Z. Naturforsch. 40b, 53—56 [1985]; eingegangen am 4. Juli/10. Oktober 1984) | | | |
Published
| 1985 | | | |
Keywords
| Crystal Structure, Bonding and Force Constants, Sulfur Halides | | | |
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| default:Reihe_B/40/ZNB-1985-40b-0053.pdf | | | | Identifier
| ZNB-1985-40b-0053 | | | | Volume
| 40 | |
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