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'Binuclear Palladium Complexes' in keywords
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1982 (1)
1Author    Werner Bertleff, Helmut WernerRequires cookie*
 Title    Ein- und zweikernige Palladiumkomplexe mit CS2 und PR3CS2 als Liganden [1] Mono-and Binuclear Palladium Complexes with CS2 and PR3CS2 as Ligands [1]  
 Abstract    The compounds Pd(PPr*3)" (n = 2 or 3) and Pd(PMePh2)4 react with CS2 to give the mononuclear complexes (PR3)2Pd(>/ 2 -CS2). In the reactions of Pd(PMe3)4 and Pd(PMe2Ph)4 with CS2 binuclear complexes [(PR3)Pcl(S2CPR3)]2 containing bridging phosphoniodithio-carboxylates as ligands are formed. [(PMe3)Pd(S 2 CPMe3)]o is also obtained from (PR3)2Pd(r? 2 -CS2) (PR3 = PPr'3, PMePho, PPI13) and PMe3. The reactions of Pd(PR3)" with the zwitter ions PMe3CS2 and PMe2PhCS2 lead to binuclear compounds f(PR3)Pd(S2CPR'3)]2 (PR3 = PPI 4 3, PMeoPh, PMePho, PPh3; PR'3 = PMe3, and PK3 = PMePh2; PR'3 = PMe2Ph). [(PMe3)Pd(S2CPMe3)]2 reacts with PMe3 with cleavage of the phosphoniodithiocarboxylate bridges to give (PMe3)2Pd(S 2 CPMe3). The formation of [(PMe3)Ni(S2CPMe3)]2 from Ni(PMe3)4 and PMe3CS2 is also described. 
  Reference    Z. Naturforsch. 37b, 1294—1300 (1982); eingegangen am 11. Juni 1982 
  Published    1982 
  Keywords    Carbondisulfidebis(phosphane)palladium Complexes, Synthesis, Reactivity, Binuclear Palladium Complexes 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1294.pdf 
 Identifier    ZNB-1982-37b-1294 
 Volume    37