| | 1 | Author
| Teruyuki Kobayashi3, Yumiko Sasakib, Tetsuya Akamatsub, Toshihiro Ishiic, YoshiakiO. Dac, Hideki Masuda3, Hisahiko Einaga3, Yuzo Nishida | Requires cookie* | | | Title
| High Activity of Binuclear Cobalt(II) Complex for Ethylene Evolution from 1-AminocycIopropane-l-carboxylic Acid in the Presence of Hydrogen Peroxide  | | | | Abstract
| The binuclear C o(II) and M n(II) complexes with H5(H XTA). where H5(H X TA) repre sents N,N'-(2-hydroxy-5-methyl-l,3-xylylene)bis(N-carboxymethylglycine), induced a strong ethylene evolution from 1-aminocyclopropane-l-carboxylic acid (ACC) in the presence of hydrogen peroxide, whereas activities of the corresponding Fe(III), N i(II), and V (III) com plexes were found negligible. Based on spectroscopic results and mass-spectral data it is proposed that a peroxide adduct of binuclear Co(II) (and M n(II)) complex with ^'-coordina tion mode interacts with ACC, which is chelated to a binuclear cobalt complex leading to facile oxidative degradation of ACC and to evolution of ethylene. | | | |
Reference
| Z. Naturforsch. 54c, 534—541 (1999); received February 25/March 31 1999 | | | |
Published
| 1999 | | | |
Keywords
| Ethylene Evolution, Binuclear Metal Complex, ACC, Hydrogen Peroxide | | | |
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| default:Reihe_C/54/ZNC-1999-54c-0534.pdf | | | | Identifier
| ZNC-1999-54c-0534 | | | | Volume
| 54 | |
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