| | 1 | Author
| Ger Vos, AnthonieJ. De Kok, GerritC. Verschoor | Requires cookie* | | | Title
| Complexes of 1,2,4-Triazoles, Part XVII The Crystal Structure of Tris-/«-(4-ethyl-l,2,4-triazole-N l ,N 2 )- (4-ethyl-l,2,4-triazole-N 1 )-aquo-bis [bis(thiocyanato-N)- nickel(II)]hydrate, Ni2(C4N3H7)4(H20)(NCS)4 *H20 (x ~ 2.5)  | | | | Abstract
| The crystal structure of Ni2(C4N3H7)4(H20)(NCS)4 • 2.5 H20 has been determined by X-ray diffraction techniques. The compound crystallizes in the monoclinic space group P2i/n with a — 15.121(4), 6= 13.237(2), c= 18.069(3), ß = 94.71(2)° and Z = 4; R = 0.040 (Rm = 0.051). The compound consists of dimeric units in which two Ni ions are bridged by three ethyltriazole (Ettrz) groups. For one Ni, two N donating NCS" groups and an Ettrz coordinating by only one N atom complete the NiNe octahedron. The other Ni atom, which is also octahedrally coordinated, has a coordinated water molecule instead of a monodentate Ettrz. | | | |
Reference
| Z. Naturforsch. 36b, 809—813 (1981); received April 2 1981 | | | |
Published
| 1981 | | | |
Keywords
| 4-Ethyl-l, 2, 4-triazole, Binuclear Compound, Hydrogen Bonding | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0809.pdf | | | | Identifier
| ZNB-1981-36b-0809 | | | | Volume
| 36 | |
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