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1992 (1)
1Author    Burkhard Niemer, TorstenW. Eidmann, W. Olfgang, BeckRequires cookie*
 Title    Kohlenwasserstoffverbrückte Metallkomplexe, XXIV [1] Pentacarbonylrhenio-substituierteThiophen-, Cyclohexadienyl-und Benzol-Komplexe von Mangan, Rhenium und Eisen Hydrocarbon Bridged Complexes, XXIV [1] Pentacarbonylrhenio Substituted Thiophene, Cyclohexadienyl and Benzene Complexes of M anganese, Rhenium and Iron  
 Abstract    The addition o f pentacarbonylrhenate to [(OC)3M n(thiophene)]+, [(OC)3M (^6-C6H 4R2)]+ (M = Mn, Re; R = H, Me, Cl) yields the er,7r-hydrocarbon bridged complexes (OC)3MnGu-774:/71-C4H 4S)Re(CO)5 and (OC)3M(Ju-^6:7 1-C6H 4R 2)Re(CO)5, respectively. The latter complexes have also been obtained from (OC)5M F B F 3 (M = Mn, Re) and C6H 5Re(CO)5. The fluxional behaviour o f the cyclohexadienyl bridged complexes is probably due to a 1,2-shift of the Re(CO)5 group. The reaction o f [Re(CO)5]-with [(/;5-C5H 5)Fe(^6-/?-C6H 4(R)Cl)]+ (R = H, Me, Cl) proceeds with substitution o f chlorine to give the heterobimetallic compounds [(75-C5H 5)Fe[^-/76^ 1-C6H 4(R)]Re(CO)5]+. 
  Reference    Z. Naturforsch. 47b, 509—516 (1992); eingegangen am 8. N ovember 1991 
  Published    1992 
  Keywords    Nucleophilic Addition o f Pentacarbonylrhenate, er, 7r-Thiophene, Cyclohexadienyl, Benzene Bridged Metal Complexes, Manganese Complexes, Rhenium Complexes 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0509.pdf 
 Identifier    ZNB-1992-47b-0509 
 Volume    47