| | 1 | Author
| Rolf Appel, Ulrich Baumeister | Requires cookie* | | | Title
| Darstellung Diorganylamino-substituierter Carbodiphosphorane [1] Synthesis of Diorganylamino Substituted Carbodiphosphoranes [1]  | | | | Abstract
| Aminolysis of the P-chlorofunctional carbodiphosphorane Ph3P = C = PPI12CI (1) affords the diorganylamino substituted phosphonium salts PI13P—CH—PPh2(NR2)] + Cl~ (3a-e, R = alkyl), which can be dehydrohalogenated in good yield by NaH to give the neutral compounds Ph3P = C — PPli2(NR2) (4a-e). The structure of the hitherto unknown amino-carbodiphosphoranes has been confirmed by 31 P{ 1 H} and 13 C{ 1 H} NMR data as well as by hydrolysis to give 5, hydrochlorination to 6b, e and methylation to 7 a, e. | | | |
Reference
| Z. Naturforsch. 35b, 513—516 (1980); eingegangen am 7. Dezember 1979 | | | |
Published
| 1980 | | | |
Keywords
| Carbodiphosphoranes, Diorganylamino Substitution, Base Reaction, 13 C NMR Spectra, 31 P NMR Spectra | | | |
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| default:Reihe_B/35/ZNB-1980-35b-0513.pdf | | | | Identifier
| ZNB-1980-35b-0513 | | | | Volume
| 35 | |
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