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1980 (1)
1Author    Rolf Appel, Ulrich BaumeisterRequires cookie*
 Title    Darstellung Diorganylamino-substituierter Carbodiphosphorane [1] Synthesis of Diorganylamino Substituted Carbodiphosphoranes [1]  
 Abstract    Aminolysis of the P-chlorofunctional carbodiphosphorane Ph3P = C = PPI12CI (1) affords the diorganylamino substituted phosphonium salts PI13P—CH—PPh2(NR2)] + Cl~ (3a-e, R = alkyl), which can be dehydrohalogenated in good yield by NaH to give the neutral compounds Ph3P = C — PPli2(NR2) (4a-e). The structure of the hitherto unknown amino-carbodiphosphoranes has been confirmed by 31 P{ 1 H} and 13 C{ 1 H} NMR data as well as by hydrolysis to give 5, hydrochlorination to 6b, e and methylation to 7 a, e. 
  Reference    Z. Naturforsch. 35b, 513—516 (1980); eingegangen am 7. Dezember 1979 
  Published    1980 
  Keywords    Carbodiphosphoranes, Diorganylamino Substitution, Base Reaction, 13 C NMR Spectra, 31 P NMR Spectra 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0513.pdf 
 Identifier    ZNB-1980-35b-0513 
 Volume    35