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1999[X]
1Author    Masahiko Matsumiya, Masatoshi Takano, Ryuzo Takagi, Reiko FujitaRequires cookie*
 Title    Electrochemical Behavior of Ba 2+ at Liquid Metal Cathodes in Molten Chlorides  
 Abstract    The electrochemcal behavior of Ba 2+ on several liquid metal electrodes (AI, Bi, Cd, Pb, Sn and Zn) in a NaCl-KCl equimolar solvent at 1000 K has been investigated by means of cyclic voltammetry and chronopotentiometry. The kinetic parameters and the diffusion coefficient for Ba 2+ were determined by cyclic voltammetry with conventional, semi-integral, semi-differential methods and chronopotentiometry. It was revealed that on a liquid Pb electrode in the NaCl-KC1 system at 1000 K the quasi-reversible cathodic reaction Ba 2+ + 2e~ + Pb —> BaPb takes place. In addition, the kinetic parameters and the diffusion coefficient agree well with the values determined by various electroanalyses. The possibility of alloy formation between Ba and Sn was also demonstrated in this paper. 
  Reference    Z. Naturforsch. 54a, 739—746 (1999); received September 13 1999 
  Published    1999 
  Keywords    Alloy Formation Reaction, Barium, Liquid Metal Cathodes, Molten Salts 
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 TEI-XML for    default:Reihe_A/54/ZNA-1999-54a-0739.pdf 
 Identifier    ZNA-1999-54a-0739 
 Volume    54