| 1 | Author
| Giacomo Cao, Giorgio Concas, Anna Corrias, Roberto Orru ', Giorgio Paschina, Barbara Simoncini, Giorgio Spano | Requires cookie* | | Title
| Investigation of the Reaction between Fe 2 0 3 and Al Accomplished by Ball Milling and Self-Propagating High-Temperature Techniques  | | | Abstract
| In this work we investigate the mechanism of product formation of the aluminothermic reaction of Fe 2 0 3 in the presence of A1 2 0 3 using Ball Milling and Self-propagating High-temperature techniques. Results obtained by experiments under either argon or air atmosphere are analysed by X-ray diffraction and Mössbauer spectroscopy, together with microstructure observations. It is shown that ball milling products are strongly affected by the kind of atmosphere, while self-propagating high-temperature ones are only weakly influenced. Reaction mechanisms taking place in these cases are proposed. While ball milling involves only solid state reactions, the formation of a melt occurs under self-propagating high-temperature conditions. | | |
Reference
| Z. Naturforsch. 52a, 539—549 (1997); received April 25 1997 | | |
Published
| 1997 | | |
Keywords
| Aluminothermic reduction, Ball Milling, Self-propagating High-temperature Synthesis, Mössbauer spectroscopy, X-ray diffraction, Mechanism of reaction | | |
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| default:Reihe_A/52/ZNA-1997-52a-0539.pdf | | | Identifier
| ZNA-1997-52a-0539 | | | Volume
| 52 | |
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