| | 1 | Author
| Edgar Niecke, Anke Nickloweit-Lüke, Reinhold Rüger, Bernt Krebs, Helmut Grewe | Requires cookie* | | | Title
| .2A 3 .3A 3 -Azadiphosphiridine -Synthese, Kristallstruktur und Eigenschaften 1,2 A 3 ,3 x 3 -Azadiphosphiridines -Synthesis, Crystal Structure and Proj)erties  | | | | Abstract
| 1,2 A 3 ,3 A 3 -Azadiphosphiridines are avaüable by elimination of hydrogenhalide from ß-and y-functional molecular frameworks and by 1 + 2 cycloaddition of phosphinidenes towards aminoiminophosphanes. In contrast to other three-membered phosphorus com-pounds, azadiphosphiridines decompose by 2 +1 cycloreversion to aminoiminophosphanes and phosphinidenes. The molecular structure of an azadiphosphiridine demonstrates the trans arrangement of the exocyclic ligands and the planarity of the endocyclic nitrogen. | | | |
Reference
| Z. Naturforsch. 36b, 1566—1574 (1981); eingegangen am 13. Juli 1981 | | | |
Published
| 1981 | | | |
Keywords
| Azadiphosphiridines, Cyclisation, Thermal Decomposition, NMR Spectra, Crystal Structure | | | |
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| ZNB-1981-36b-1566 | | | | Volume
| 36 | |
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