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'Azadiferrathia' in keywords Facet   Publication Year 1996  [X]
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1996[X]
1Author    Max Herberhold, E. Bertholdt, WolfgangM. Iliu, BerndW. RackmeyerRequires cookie*
 Title    N-Functionalization of the Tetrahedrane Fe2(CO)6(/z-SNH)  
 Abstract    The azadiferrathia tetrahedrane, Fe2(CO)6(£/-SNH) (1), was deprotonated to give the anion [Fe2(CO)6(/J-SN)]_ (2) which reacts with halides of phosphorus, arsenic, silicon, germanium, tin and boron by formation of element-nitrosen bonds. The new compounds were characterized by their IR. N M R ('H , mB, i3C, i5N, 29S i,3 P, m S n)and mass spectra. The molecular structure of [Fe2(CO)6(A/-SN-SiMe2CH2-)]2 (11) was determined by X-ray structure analysis (space group P i; triclinic; a = 799.8(2), b = 958.5(2), c = 1035.7(2) pm, a = 86.30(2)°, (3 = 81.27(2)°, 7 = 69.90(2)°). 
  Reference    Z. Naturforsch. 51b, 1283—1289 (1996); received March 27 1996 
  Published    1996 
  Keywords    Azadiferrathia, Tetrahedrane, Cluster Anion, Element-Nitrogen Bonds, NMR Spectra 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1283.pdf 
 Identifier    ZNB-1996-51b-1283 
 Volume    51