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'Azaborolinyl Sandwich Complexes' in keywords
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1983 (1)
1Author    Günter Schmid, Roland BoeseRequires cookie*
 Title    Azaborolinyl Complexes, IX [1] The Crystal and Molecular Structures of Two Isomers of Bis(l-ter£-butyl-2-methyl-??-l,2-azaborolinyl)cobalt  
 Abstract    The crystal and molecular structures of two isomers of bis(l-£er£-butyl-2-methyl-??-l,2-azaborolinyl)cobalt have been determined by single-crystal X-ray diffraction methods. Isomer 1 shows a clockwise, isomer 2 an anti-clockwise conformation of the azaborolinyl rings. In both compounds the azaborolinyl rings have staggered orientations with opposite positions of the tferi-butyl groups. The rings in 1 and 2 are slipped so that the three ring carbon atoms are closer to the cobalt atom than the BN groups. The staggered orientation of the ligands in 2 is probably due to a packing effect, as in similar sandwich complexes the anti-clockwise conformers show eclipsed orientation. 
  Reference    Z. Naturforsch. 38b, 485—492 (1983); eingegangen am 12. November 1982 
  Published    1983 
  Keywords    Azaborolinyl Sandwich Complexes, Cobalt, Isomers, X-Ray 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0485.pdf 
 Identifier    ZNB-1983-38b-0485 
 Volume    38