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'Arylfluoroarsonium' in keywords
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1981 (1)
1Author    FrancisL. Tanzella, Neil BartlettRequires cookie*
 Title    Quantitative Synthesis of (C6H5)2AsF2+AsF6-and (C6H5)2A8F3 via Interaction of Benzene with Arsenic Pentafluoride  
 Abstract    Benzene reacts quantitatively with AsFs to give (C6H5)2AsF2 + AsF6-, the first reported aryl or alkyl fluoroarsonium(V) salt. This reacts quantitatively with CsF to give (CeH5)2AsF3 and CsAsF6. Interaction of (C6H5)2AsF3 with AsF5 reconstitutes the fluoro-arsonium salt. Variable temperature 19 F NMR studies show (CÖHS^ASFS to be a rigid trigonal bipyramid, with the phenyl groups in equatorial positions. 
  Reference    Z. Naturforsch. 36b, 1461—1464 (1981); received May 18 1981 
  Published    1981 
  Keywords    Arylfluoroarsonium, Arsenic, Benzene, Substitution 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1461.pdf 
 Identifier    ZNB-1981-36b-1461 
 Volume    36