| | 1 | Author
| C. U., D. Osterloh, Hk Müller-Buschbaum | Requires cookie* | | | Title
| Das erste Oxocuprat/-Arsenat mit Kupfer in gemischter Valenz  | | | | Abstract
| ,56C u o , 4 4) C u (A s 0 4)3 The First O xocuprate/Arsenate Containing Mixed Valent Copper: Cu(Mg2.56Cu0.44)C u(A sO4) 3 Single crystals of Cu(Mg2 56Cu0 44)C u (A s0 4)3 have been prepared by C 0 2-LASER technique and investigated by X-ray diffraction methods. The light blue crystals show monoclinic sym metry, space group C2h-C 2/c, a = 11.897, b = 12.855, c -6.688 A, ß = 113.06°, Z = 4. The structure type is characterized by A s 0 4 tetrahedra, dumb-bell-like coordinated Cu(I), twisted C u 0 4 square polygons and octahedra statistically occupied by Mg/Cu2+. | | | |
Reference
| Z. Naturforsch. 49b, 589—592 (1994); eingegangen am 14. Januar 1994 | | | |
Published
| 1994 | | | |
Keywords
| Magnesium, Copper, Arsenic Oxide, Crystal Structure | | | |
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| default:Reihe_B/49/ZNB-1994-49b-0589.pdf | | | | Identifier
| ZNB-1994-49b-0589 | | | | Volume
| 49 | |
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