| | 1 | Author
| Jochen Eilermann, Martin Lietz | Requires cookie* | | | Title
| Chemie polyfunktioneller Liganden, 67 [1]  | | | | Abstract
| Die Darstellung von l.l.l-Tris(dichlorarsinomethyl)ethan, Ethan-l.l.l-tris(methylarsonsäure), 1.1.1-Tris (arsinomethyl)ethan und einem neuen Organocyclotriarsan Chemistry of Polyfunctional Ligands, 67 [1] The Preparation of l.l.l-Tris(dichloroarsinomethyl)ethane, Ethane-l.l.l-tris(methylarsonic acid), l.l.l-Tris(arsinomethyl)ethane and of a New Organocyclotriarsane l,l,l-Tris(dichlorarsinomethyl)ethane, CH3C(CH2AsCl2)3 (5) can be obtained in the reaction of CH3C(CH2AsNC6H4CH3)3 (4) with gaseous HCl. The heteroadamantane CH3C(CH2AsO)3 (6) reacts with AsCl3 or PC13 yielding also 5. CH3C(CH2AsO)3, CH3C(CH2AsS)3 and CH3C(CH2AsI 2)3 are oxidized with H202 to give CH3C[CH2As(0)(0H)2]3 (7) and CH3C[CH2As(0)(0H)2]3 • H20 (7 a). CH3C(CH2AsI2)3 and C(CH2AsI2)4 can be reduced with LiAlH4 to give CH3C(CH2AsH2)3 (9) and C(CH2AsH2)4 (12). Oxidation of 9 and 12 leads to the cyclotriarsane compounds CH3C(CH2As)3 (10) and H2AsCH2C(CH2As)3 (13). | | | |
Reference
| (Z. Naturforsch. 37b, 73—80 [1982]; eingegangen am 29. Juni/21. September 1981) | | | |
Published
| 1982 | | | |
Keywords
| Arsenic Compounds, Organocyclotriarsane, Vibrational Spectra, *H NMR Spectra, Mass Spectra | | | |
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| default:Reihe_B/37/ZNB-1982-37b-0073.pdf | | | | Identifier
| ZNB-1982-37b-0073 | | | | Volume
| 37 | |
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