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1990 (1)
1982 (1)
1Author    Annegret Lipka, Dietrich MootzRequires cookie*
 Title    von Antimontribromid mit Biphenyl, 2 SbBr3 * C12H10 The Crystal Structure of the 2 : 1 Adduct of Antimony Tribromide with Biphenyl, 2SbBr3-Ci2Hio  
 Abstract    The crystal structure of 2 SbBr3 • biphenyl consists of pyramidally shaped SbBr3 molecules and planar biphenyl molecules which form a centrosymmetric complex through bonding of the Sb atoms to the phenyl rings. The distance of the Sb atoms to the phenyl ring planes is 323 pm. Taking into account intramolecular bonds Sb-Br at an average of 250.9 pm, an intermolecular Sb---Br contact at 369.5 pm and the .-r-donor-acceptor inter-action the Sb coordination is distorted -octahedral. The structure is discussed with regard to related compounds. 
  Reference    Z. Naturforsch. 37b, 695—698 (1982) 
  Published    1982 
  Keywords    Crystal Structure, Antimony Trihalides, Biphenyl 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0695.pdf 
 Identifier    ZNB-1982-37b-0695 
 Volume    37 
2Author    Siegfried Pohl, W. Olfgang Saak, R. Ain, Er Lotz, Detlev HaaseRequires cookie*
 Title    Zur Existenz schwacher Wechselwirkungen zwischen Sb(III) und Phenylgruppen: Sb2 Br6 (SPPh3)2, Sb2 I6 (SePPh3 ) 2 * 2 CH2 C12, Sb4 Br12(SPM e2 Ph) 4 und (Ph4 P)2 Sb2 Br8 * CH3CN  
 Abstract    On the Existence o f W eak In teractio n s between Sb(III) and Phenyl G roups: Sb2Br6(SP Ph3)2, Sb2I6(SeP Ph3)2 • 2 C H 2C12, Sb4B r12(SPM e2Ph)4 and (Ph4P)2Sb2Br8 • C H 3CN The com pounds Sb2Br6(SPPh3)2 (1), Sb2I6(SePPh3)2-2 C H 2C12 (2), and Sb4Br12(SPMe2Ph)4 
  Reference    Z. Naturforsch. 45b, 1355 (1990); eingegangen am 6. März 1990 
  Published    1990 
  Keywords    Sb(III)-Phenyl Interaction, Antimony Trihalides, Crystal Structure 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-1355.pdf 
 Identifier    ZNB-1990-45b-1355 
 Volume    45