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'Antimony Methyl Halides' in keywords Facet   Publication Year 1976  [X]
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1Author    Susanne Elbel, HeindirkTom DieckRequires cookie*
 Title    Photoelektronenspektren von Verbindungen der V. Hauptgruppe, III 1 Methylhalogenverbindungen MeEHal2 und Me2EHal Photoelectron Spectra of Group V Compounds, III 1 Methylhalogen Compounds MeEHal2 and Me2EHal  
 Abstract    The He I photoelectron spectra of certain MeEHal2 and MeaEHal compounds (E = (N), P, As, Sb; Hal = (F), Cl, Br, J; Me = CH3) are interpreted in terms of a "composite molecule" approach derived for C3v/Cs systems. Although an "internal standard" is missing here, substituent group-orbitals (njjai, C-H) may be classified with respect to their orien-tations in space (R, V, T). Ionisation energies are assigned according to this assumption. PE data of the isoelectronic EMe3/EHal3 compounds and of related molecules (Me2EH, MePH2, CF3PBr2) as well as EHMO calculations with partial inclusion of spin orbit coupling are used to confirm the assignments given for Me2EHal/MeEHal2 series. Correlations between PE ionisation energies (e.g. nE (IE)) and molecular or atomic properties are critically revised and discussed. 
  Reference    (Z. Naturforsch. 31b, 178—189 [1976]; eingegangen am 1. September 1975) 
  Published    1976 
  Keywords    Photoelectron Spectra, Nitrogen, Phosphorus, Antimony Methyl Halides, n-Ionizations 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-0178.pdf 
 Identifier    ZNB-1976-31b-0178 
 Volume    31