| | 1 | Author
| Annegret Lipka, Hartmut Wunderlich | Requires cookie* | | | Title
| Die Kristallstruktur des l:l-Komplexes von Antimontrichlorid und 2.2'-Bipyridin The Crystal Structure of the 1:1 Complex of Antimony Trichloride and 2,2'-Bipyridine  | | | | Abstract
| The crystal structure of the complex compound of SbCL with a chelating bipyridyl group was determined. Sb(CioH8N2)Cl3 crystallizes in the space group P2i/c with a = 818.9(4), b = 695.8(7), c = 2331.3(12) pm, ß = 103.59(4)° and Z = 4 molecules per unit cell. The SbCL fragment is T-shaped with <Sb-Cl> at 254.7 pm. Taking into account also the N atoms of the chelating 2,2'-bipyridyl group (<Sb-N> = 228.1 pm) and an inter-molecular Sb-Cl contact at 334.0 pm the Sb coordination is distorted octahedral. | | | |
Reference
| Z. Naturforsch. 35b, 1548—1551 (1980); eingegangen am 22. August 1980 | | | |
Published
| 1980 | | | |
Keywords
| Stereochemistry, Crystal Structure, Antimontrichloride, 2, 2'-Bipyridine | | | |
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| default:Reihe_B/35/ZNB-1980-35b-1548.pdf | | | | Identifier
| ZNB-1980-35b-1548 | | | | Volume
| 35 | |
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