| | 1 | Author
| Ayhan Elmali3, Yalcin Elermana, Ingrid Svobodab, Hartmut Fuessb, Klaus Griesar0, Wolfgang Haasec | Requires cookie* | | | Title
| Structure and Magnetic Properties of a Dinuclear Copper(II) Complex  | | | | Abstract
| [Cu2L] (L=N-2-hydroxy-4-methylphenyl-4-oxo-2-pentalketimine) was synthesized and its crystal structure determined. C24H?6Cu2N204 monoclinic space group P2|/n with a= 10.978(2), 17.045(3), c= 11.958(2) Ä, ß = 101.89(1)°, V = 2189.6(7) A3,Z = 4. Two copper(II) atoms in a distorted square-planar coordination are bridged by two oxygen atoms to form a dinuclear unit. The copperfll) centers are separated by 3.025(1) A and antiferro-magnetically coupled (7=-222.3 cm), which follows from temperature-dependent magnetic susceptibility measurements in the range 4.2 to 300 K. | | | |
Reference
| Z. Naturforsch. 52b, 157—161 (1997); received September 30 1996 | | | |
Published
| 1997 | | | |
Keywords
| Dinuclear Cu(II) Complex, X-Ray, Structure, Magnetic Properties, Antiferromagnetic Coupling | | | |
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| ZNB-1997-52b-0157 | | | | Volume
| 52 | |
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