| | 1 | Author
| Stefan Horstmann, Wolfgang Schnick | Requires cookie* | | | Title
| Synthese, Kristallstruktur und Eigenschaften von 1,1,3,3,3-Pentaamino- l-th io -l A \3 A 5-diphosphaz-2-en (NH2)2P(S)N=P(NH2)3 Synthesis, Crystal Structure, and Properties of 1,1,3,3,3-Pentaam ino-l-thio-l A5,3A5-diphosphaz-2-ene (N H 2)2P(S)N =P(NH 2)3  | | | | Abstract
| (NH2)2P(S)N=P(NH2)3 has been prepared by a two step synthesis. Suitable single crystals were obtained from an acetonitrile solution in a temperature gradient between 60 °C and room temperature. The crystal structure of (NH->)tP(S)N=P(NH->)3 has been determined by single cry stal X-ray methods (P2,/c, a = 9 9 8 .2 7 (9)> '= 762.78(8), c = 1007.70(15) pm, ß = 107.340(7)°, Z = 4). In the crystal structure each hydrogen atom is subject to a hydrogen bond. Four N-H -N hydrogen bonding interactions per molecule build up a framework connecting two molecules in eight-membered rings. Each sulfur atom shows six distances N -H -S in the range of weak hydrogen bonding interactions. | | | |
Reference
| Z. Naturforsch. 52b, 490—95 (1997); eingegangen am 18. Dezember 1996 | | | |
Published
| 1997 | | | |
Keywords
| Aminophosphazenes, Synthesis, Crystal Structure, Hydrogen Bonding | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/52/ZNB-1997-52b-0490.pdf | | | | Identifier
| ZNB-1997-52b-0490 | | | | Volume
| 52 | |
|
