1 | Author | Z. Naturforsch | Requires cookie* |
Title | Aminolyse von Cp2ZrCl{P(SiMe3)2} -Synthese und Molekülstruktur von Cp2ZrCl(NHPh) ![]() | ||
Abstract | The reaction of Cp2ZrCl{P(SiM e3)2} with aniline yields the terminal zirconocene phenyl amido com plex Cp2Z rCl(N H Ph) (1) and H P(SiM e3)2. 1 was characterized spectroscopically (n.m.r., i.r.) and by X-ray structure determination (monoclinic space group P 2 {ln, a -6.589(2), b = 19.978(3), c = 13.512(2) Ä , ß = 101.09(2)° (at 200 K)). The NHPh group is planar with Z r -N 2.116(10) A. | ||
Reference | Z. Naturforsch. 50b, 1359—1361 (1995); eingegangen am 24. Februar 1995 | ||
Published | 1995 | ||
Keywords | Aminolysis, Zirconocene Phosphido Complex Zirconocene Phenylamido Complex, Crystal Structure | ||
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