| 1 | Author
| H. H. Baalmann, R. Keizer, J. C. Van De Grampel, C. Kruk | Requires cookie* | | Title
| Derivatives of eis-NPC12(NS0C1)2 and (NPC12)2NS0C1, Part IX [1] Substitution Reactions of eis-NPC12(NS0C1)2 with Piperidine  | | | Abstract
| Aminolysis of cis-NPCl2(NSOCl)2 by piperidine in acetonitrile at room temperature proceeds via a non-geminal substitution pattern. During the first substitution step the reactivity of a SOCl-centre appears to be greater than that of a PCl2-centre. The second and third substitution step successively take place at the PC12-and remaining SOCl-centre. The different isomeric forms of the mono-, bis-, tris-, and tetrakis(piperidino) derivatives are characterized by means of 31 P NMR data. Application of 13 C NMR leads in two cases to a structure assignment. | | |
Reference
| Z. Naturforsch. 33b, 959—963 (1978); received June 26 1978 | | |
Published
| 1978 | | |
Keywords
| Aminolysis, Reaction Pattern, Structure Assignment | | |
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| default:Reihe_B/33/ZNB-1978-33b-0959.pdf | | | Identifier
| ZNB-1978-33b-0959 | | | Volume
| 33 | |
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