| | 1 | Author
| Peter Paetzold, Günther Schimmel | Requires cookie* | | | Title
| ungesättigter Stickstoffbasen Boration Reactions with the N-Oxides and m-Imines of Unsaturated Nitrogen Bases  | | | | Abstract
| -Dipolar reagents with an unsaturated CNO-or CNN-skeleton undergo 1,3-organo-boration by triorganoboranes. On the other hand, the unsaturated NNO-skeletons in azoxybenzene or nitrous-oxide are reduced to the corresponding NN-fragment by trialkyl-boranes. The 1,3-addition of aminoborane Cl2BNMe2 to the aldimineoxide PhHC = NMe-0 represents one of the rare examples of analogous reactivity of BN-and CC-double bonds. O-Borylhydroxylamines PhHCR-NMe-OBR2 are reduced by BR'3 to PhHCR-NMe-BR'2 and R'0-BR2. Similar reduction products are isolated from liquid-phase thermolysis of PhHCEt-NMe-OBEt2 (16), whereas gas-phase thermolysis of 16 gives PhCH = NMe, (EtBO)3, and C4HI0. | | | |
Reference
| Z. Naturforsch. 35b, 568—577 (1980); eingegangen am 6. Dezember 1979 | | | |
Published
| 1980 | | | |
Keywords
| O-Borylhydroxylamines, Borylhydrazines, 2-Borylhydrazones, Organoboration, Aminoboration 1, 3 | | | |
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| default:Reihe_B/35/ZNB-1980-35b-0568.pdf | | | | Identifier
| ZNB-1980-35b-0568 | | | | Volume
| 35 | |
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