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'Amine Complexes' in keywords Facet   Publication Year 1998  [X]
Facet   section ZfN Section B:Volume 053  [X]
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1Author    PeterG. Jones, Birte AhrensRequires cookie*
 Title    Gold(I)-Komplexe mit Aminliganden, II [1]. (Methylpyridin)-Komplexe von Gold(I) Gold(I) Complexes with Amine Ligands, II. Methylpyridine Complexes of Gold(I)  
 Abstract    Gold(I) complexes of overall formula LAuCl (L = various methylpyridines) are non-con­ ducting in acetone. X-ray structure analyses show that the solid state structure of the cor­ responding complex 1 (L = 2-picoline) is molecular; the 3-picoline derivative 2 is however ionic (L2A u)+(AuCl2)-. 3-Picoline forms a molecular complex LAuC6F5 (3) and also the ionic (L2Au)+(SbF6)_ (4). Complexes 1, 2 and 4 display short A u--A u contacts, leading to chains of gold atoms; additionally, complexes 3 and 4 show weak Au-F contacts. The (3-picoline)-gold(III) complex /rans-(L2AuCl2)+(SbF6)_ (5) was obtained as a by-product; it too contains short Au-F contacts. 
  Reference    Z. Naturforsch. 53b, 653—662 (1998); eingegangen am 6. April 1998 
  Published    1998 
  Keywords    Gold(l), Pyridine, Amine Complexes, X-Ray Data 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0653.pdf 
 Identifier    ZNB-1998-53b-0653 
 Volume    53