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1999 (1)
1Author    H. Oppermann, H. Dao Quoc, A. Morgenstern, Prof ManfredRequires cookie*
 Title    Thermisches Verhalten von festem LaAlCl6 und chemischer Transport von LaCl3 mit AICI3 Thermical Behaviour of Solid LaAlCl6 and Chemical Transport of LaCl3 with A1C13  
 Abstract    The thermodynamical data of solid aluminium lanthanum chloride LaAlCl6 have been ob­ tained by determination of the decomposition equilibria from total pressure measurements. The melting diagram was determined by DTA. The chemical transport of LaCl3 with A1C13 is suggesting the existence of the gaseous complex LaAl3C l12. The data are: Z\H(LaAlCl6 f 298) =-427,1 ±2,5 kcal/mol, S°(LaAlCl6.f.298) = 61 ±2,5 cal/K-mol, _AH(LaAl3C l12 g 298) =-712 ± 7 kcal/mol, S°(LaAl3C l12>g,298) = 205 ± 3 cal/K-mol. 
  Reference    Z. Naturforsch. 54b, 1410—1416 (1999); eingegangen am 15. Juli 1999 
  Published    1999 
  Keywords    Aluminium Lanthanum Chloride, Thermal Decomposition, Chemical Transport, Enthalpy, Entropy 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-1410.pdf 
 Identifier    ZNB-1999-54b-1410 
 Volume    54