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1990 (1)
1Author    Andreas Ketter, R. Udolf, Herrmann, GarchingF R GRequires cookie*
 Title    Chiral Lewis Acids as Enantioselective Catalysts in the Diels-Alder Reaction and the Allylic Addition to Aldehydes  
 Abstract    The efficiency o f chiral Lewis acids derived from TiCl4 or A1(Bu/)2C1 with chiral chelating ligands as catalysts for som e enantioselective reactions was evaluated. The Diels-Alder reac­ tion between isoprene and methyl acrylate gave the cyclohexene derivative with up to 32% enantiomeric excess (e.e.). The reaction o f 3-methylbutanal with allyltrimethylsilane led to 6-m ethylhept-l-en-4-ol with up to 36% e.e. 
  Reference    Z. Naturforsch. 45b, 1684—4 (1990); received June 11 1990 
  Published    1990 
  Keywords    Chiral Lewis Acids, Allylic A ddition, Enantioselective Catalysis, Diels-Alder Reaction 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-1684.pdf 
 Identifier    ZNB-1990-45b-1684 
 Volume    45