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'Allyl Complexes' in keywords Facet   Publication Year 1982  [X]
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1982[X]
1Author    JaapN. Louwen, Jaap Hart, DerkJ. Stufkens, Ad OskamRequires cookie*
 Title    The Hei and HeH Photoelectron Spectra of [Fe*? 3 -C3H5(CO)3X] and [Fe^ 3 -C4H7 (CO)3X] (X = Cl, Br, I) and [CoC3H5(CO)3]  
 Abstract    By means of UV photoelectron spectroscopy (UPS) the electronic structures of [Fe^3.C3H5(CO)3X], [Fe^3-(2-CH3C3H4)(CO)3X] (X = Cl, Br, I) and [Co(C3H5)(CO)3] have been studied. Detailed assignments are possible and surprisingly low ionization energies (as low as 8.19 eV) are found for iodine lone pair type Orbitals. From the spectra a large difference in n backbonding is found between the cobalt and iron complexes. 
  Reference    Z. Naturforsch. 37b, 179—185 (1982); received September 29 1981 
  Published    1982 
  Keywords    Photoelectron Spectra, Iron, Cobalt, Allyl Complexes 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0179.pdf 
 Identifier    ZNB-1982-37b-0179 
 Volume    37