| 1 | Author
| Gerd Becker, Gudrun Gresser, Werner Uhl | Requires cookie* | | Title
| Acyl-und Alkylidenphosphane, XV [1] 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl  | | | Abstract
| In the presence of small amounts of solid sodium hydroxide, [2,2-dimethyl-l-(trimethyl-siloxy)propylidene]-trimethylsilylphosphine reacts at -f 20 °C to give hexamethyldisil-oxane and 2,2-dimethylpropylidynephosphine (2). In contrast to similar alkylidyne-phosphines this compound is stable at room temperature. The IR and mass spectrum are discussed, and iH, 13 C and 31 P NMR spectral data are given. | | |
Reference
| (Z. Naturforsch. 36b, 16—19 [1981]; eingegangen am 3. Oktober 1980) | | |
Published
| 1981 | | |
Keywords
| Alkylidynephosphines, 2, 2-Dimethylpropylidynephosphine, P-C Triple Bond | | |
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| default:Reihe_B/36/ZNB-1981-36b-0016.pdf | | | Identifier
| ZNB-1981-36b-0016 | | | Volume
| 36 | |
|