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1996 (1)
1Author    Cl Walter, Frank, GuidoJ. ReißRequires cookie*
 Title    Spezielle Alkylammoniumhexachlorometallate, II [1] Synthese und Kristallstruktur von Bis(l,2-diammoniopropan)hexachlororhodat(III)-chlorid, [H3N-CH(CH3)-CH2-NH3]2[RhCl6]Cl Alkylammonium Hexachlorometallates, II [1] Synthesis, and Crystal Structure of Bis( 1,2-diammoniopropane) Hexachlororhodate(III) Chloride, (H3N-CH(CH3)-CH9-NH3]-,|RhCl6]  
 Abstract    Bis(1,2-diammoniopropane) hexachlororhodate(III) chloride, [H ^N -CH tCI-fO -CH i-N H ^ [RhCl6]Cl (1) has been obtained by the reaction of rhodium(III) chloride with rac-1,2-diammoniopropane dihydrochloride in hydrochloric acid solution. The quasi-ternary com ­ pound, which crystallizes in the orthorhombic space group Pbca (a -11.0007(13) A, b = 22.181(2) A, c = 14.638(2) A, V = 3571.7(7) Ä \ T = -1 2 0 °C, Z -8) contains two crystallographically independent 1,2-diammoniopropane ions beside one hexachlororhodate and one chloride ion. One of the cations shows a R/S-S/R-disorder of enantiomeric pairs in the centrosymmetric crystal lattice. The packing scheme is determined by a complex framework of hydrogen bonds. 
  Reference    Z. Naturforsch. 51b, 1459—1463 (1996); eingegangen am 9. April 1996 
  Published    1996 
  Keywords    Hexachlororhodate, Alkylammonium Salt, Crystal Structure, Hydrogen Bonding 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1459.pdf 
 Identifier    ZNB-1996-51b-1459 
 Volume    51