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'Alkyl arylphosphinothioformamides' in keywords
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1987 (1)
1Author    Udo Kunze, Rolf TittmannRequires cookie*
 Title    Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe  
 Abstract    A series of alkyl-arylsubstituted N-methyl phosphinothioformamides, R(Ph)PC(S)NHMe (2 a—g), with varying bulkiness of the alkyl rest was synthesized from the racemic secondary phosphines la—g and methyl isothiocyanate. 'H and 13 C NMR spectra of 2a—g reveal signal sets of diastereotopic nuclei due to the asymmetry of the molecule. The chemical shift and coupling constants were confirmed by simulation in case of 2b, c. The vicinal 31 P— 13 C cou-plings of the menthyl and neomenthyl compounds 2f, g show an "anti-Karplus" behaviour CJ(gauche) > ? J(trans)) and allow the conformational assignment of the alicyclic group. The 31 P chemical shifts of 2a—d give a linear correlation with the cone angle of the alkyl substituents quoted from literature. 
  Reference    (Z. Naturforsch. 42b, 77—83 [1987]; eingegangen am 8. August 1986) 
  Published    1987 
  Keywords    Alkyl-arylphosphinothioformamides, Menthyl and Neomenthyl Derivatives, NMR Spectra, Conformational Analysis, Substituent Influence 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0077.pdf 
 Identifier    ZNB-1987-42b-0077 
 Volume    42