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'Alkali Metal Reduction' in keywords Facet   Publication Year 1981  [X]
Facet   section ZfN Section B  [X]
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1Author    Mit Alkylderivaten Von Bor, GalliumUnd Aluminium, Indium, Wolfgang KaimRequires cookie*
 Title    Koordinationsverbindungen des reduzierten Pyrazins  
 Abstract    The alkyls MR3 (M = B, AI, Ga, In) react with pyrazine (Pz) and sodium in THF to yield persistent radical complexes Pz(MR2)2 ,+ MR4~ (1). Use of TIR3 leads to rapid deposi-tion of thallium metal. The formation of these ionic complexes 1 is the result of MR3 dissociation into +MR2 and -MR4 ions. All radicals have been identified and characterized by ESR; the data reveal the influence of N3B back bonding in the boron derivative. 
  Reference    Z. Naturforsch. 36b, 677—682 (1981); eingegangen am 6. März 1981 
  Published    1981 
  Keywords    Pyrazine, Alkali Metal Reduction, Group III Alkyls, Radical Complexes, ESR Spectra 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0677.pdf 
 Identifier    ZNB-1981-36b-0677 
 Volume    36