1 | Author | Heinz Hoberg, Klaus Sümmermann | Requires cookie* |
Title | Nickel(0)-katalysierte Synthese von Iminen aus Isocyanaten und Aldehyden Nickel(O) Catalysed Synthesis of Imines from Isocyanates and Aldehydes ![]() | ||
Abstract | The influence of different ligands upon the nickel(0)-catalysed formation of imines from iso cyanates and aldehydes is reported. Carbonyl-free nickel(O) systems are found to be more active and provide a simple synthesis of imines. The catalysis proceeds via a five-membered metalla-cycle, which has been isolated and characterized. | ||
Reference | Z. Naturforsch. 39b, 1032—1036 (1984); eingegangen am 2. März 1984 | ||
Published | 1984 | ||
Keywords | Nickel(O), Isocyanates, Aldehydes, Imines, Reductive Elimination Process | ||
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